Issue 3, 2004
From the journal:

Chemical Communications

Contrasting coordination behaviour of 22-membered chalcogenaaza (Se, Te) macrocylces towards Pd(ii) and Pt(ii): Isolation and structural characterization of the first metallamacrocyle with a C–Pt–Se linkage†

Snigdha Panda,a   Harkesh B. Singh*a  and  Ray J. Butcherb  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology, Bombay, Mumbai 400076, India
E-mail: chhbsia@chem.iitb.ac.in

b Department of Chemistry, Howard University, Washington D.C. 20059, USA

Abstract

Interaction of the 22-membered selenaaza macrocyle 3 with Pt(II) leads to the formation of the novel cationic Pt(IV) metallamacrocylic complex 5via the oxidative addition of a C–Se bond to Pt(II), whereas corresponding reactions of 3 and 4 with Pd(II) afford cationic complexes 6 and 7 with differing ligating properties.

Graphical abstract: Contrasting coordination behaviour of 22-membered chalcogenaaza (Se, Te) macrocylces towards Pd(ii) and Pt(ii): Isolation and structural characterization of the first metallamacrocyle with a C–Pt–Se linkage

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Article information

DOI
https://doi.org/10.1039/B312358H
Article type
Communication
Submitted
06 Oct 2003
Accepted
24 Nov 2003
First published
08 Jan 2004

Chem. Commun., 2004, 322-323

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Contrasting coordination behaviour of 22-membered chalcogenaaza (Se, Te) macrocylces towards Pd(II) and Pt(II): Isolation and structural characterization of the first metallamacrocyle with a C–Pt–Se linkage

S. Panda, H. B. Singh and R. J. Butcher, Chem. Commun., 2004, 322 DOI: 10.1039/B312358H

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