Issue 7, 2004
From the journal:

Chemical Communications

On the relative migratory aptitudes of carbon and heteroatoms in borate complexes. A surprising α-thia effect

Jonathan M. Stoddarda  and  Kenneth J. Shea*a  

* Corresponding authors

a Department of Chemistry, University of California, Irvine, CA 92697-2025, USA
E-mail: kjshea@uci.edu
Fax: +1 949 824 2210

Abstract

Dimethylsulfoxonium methylide reacts with dicyclohexyl(α-thiophenylmethyl)methylborane via 1,2-alkyl migration and alkyldithiaborolane via 1,2-sulfur migration.

Graphical abstract: On the relative migratory aptitudes of carbon and heteroatoms in borate complexes. A surprising α-thia effect

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Article information

DOI
https://doi.org/10.1039/B311292F
Article type
Communication
Submitted
15 Sep 2003
Accepted
11 Feb 2004
First published
27 Feb 2004

Chem. Commun., 2004, 830-831

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On the relative migratory aptitudes of carbon and heteroatoms in borate complexes. A surprising α-thia effect

J. M. Stoddard and K. J. Shea, Chem. Commun., 2004, 830 DOI: 10.1039/B311292F

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