Issue 2, 2004
From the journal:

Chemical Communications

Synthesis and structural characterization of the first unsymmetrical diarylpalladium complex trans-Pd(C6F5)(2,4,6-C6F3H2)(PEt3)2, derived from transmetallation between 2,4,6-trifluorophenylboronic acid and trans-Pd(C6F5)I(PEt3)2

Yasushi Nishihara,a   Hiroyuki Onoderaa  and  Kohtaro Osakada*a  

* Corresponding authors

a Chemical Resources Laboratory, Tokyo Institute of Technology, Nagatsuta, Yokohama 226-8503, Japan
E-mail: kosakada@res.titech.ac.jp
Fax: +81 45 924 5224
Tel: +81 45 924 5224

Abstract

The reactions of 2,4,6-trifluorophenylboronic acid with aryl(iodo)palladium(II) complexes, trans-Pd(C6F5)I(PR3)2 (PR3 = PEt3, PMe2Ph, PMePh2) in the presence of Ag2O afforded trans-Pd(C6F5)(2,4,6-C6F3H2)(PR3)2 which are stabilized by fluorine atoms in the ortho positions.

Graphical abstract: Synthesis and structural characterization of the first unsymmetrical diarylpalladium complex trans-Pd(C6F5)(2,4,6-C6F3H2)(PEt3)2, derived from transmetallation between 2,4,6-trifluorophenylboronic acid and trans-Pd(C6F5)I(PEt3)2

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Article information

DOI
https://doi.org/10.1039/B308741G
Article type
Communication
Submitted
30 Jul 2003
Accepted
05 Nov 2003
First published
04 Dec 2003

Chem. Commun., 2004, 192-193

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Synthesis and structural characterization of the first unsymmetrical diarylpalladium complex trans-Pd(C6F5)(2,4,6-C6F3H2)(PEt3)2, derived from transmetallation between 2,4,6-trifluorophenylboronic acid and trans-Pd(C6F5)I(PEt3)2

Y. Nishihara, H. Onodera and K. Osakada, Chem. Commun., 2004, 192 DOI: 10.1039/B308741G

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