Issue 11, 2003
From the journal:

Photochemical & Photobiological Sciences

Asymmetric synthesis in a Norrish type II cleavage reaction induced by crystal chirality†

André B. Charette,b   Kenneth C. W. Chong,a   Jean-François Fournier,b   Brian Patricka  and  John R. Scheffer*a  

* Corresponding authors

a Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, Canada V6T 1Z1
E-mail: Scheffer@chem.ubc.ca

b Département de Chimie, Université de Montréal, Case Postale 6128, succursale Centre-ville, Montréal, Canada H3C 3J7

Abstract

Moderate to high enantiomeric excesses for the cis and trans olefinic products of a Norrish type II cleavage reaction have been obtained for the first time through the use of the solid-state ionic chiral auxiliary approach.

Graphical abstract: Asymmetric synthesis in a Norrish type II cleavage reaction induced by crystal chirality

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Article information

DOI
https://doi.org/10.1039/B309256A
Article type
Communication
Submitted
04 Aug 2003
Accepted
03 Sep 2003
First published
12 Sep 2003

Photochem. Photobiol. Sci., 2003,2, 1052-1055

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Asymmetric synthesis in a Norrish type II cleavage reaction induced by crystal chirality

A. B. Charette, K. C. W. Chong, J. Fournier, B. Patrick and J. R. Scheffer, Photochem. Photobiol. Sci., 2003, 2, 1052 DOI: 10.1039/B309256A

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