Issue 18, 2003
From the journal:

Organic & Biomolecular Chemistry

1,5-Asymmetric induction of chirality using π-allyltricarbonyliron lactone complexes: highly diastereoselective synthesis of α-functionalised carbonyl compounds

Christopher J. Hollowood,a   Steven V. Ley*a  and  Edward A. Wrighta  

* Corresponding authors

a Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: svl1000@cam.ac.uk
Fax: +44 (01223) 336442
Tel: +44 (0)1223 336398

Abstract

Silyl enol ethers derived from ketone functionalised π-allyltricarbonyliron lactone complexes undergo highly diastereoselective carbon–fluorine and carbon–oxygen bond formation reactions with excellent control at the α-stereogenic centre.

Graphical abstract: 1,5-Asymmetric induction of chirality using π-allyltricarbonyliron lactone complexes: highly diastereoselective synthesis of α-functionalised carbonyl compounds

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Article information

DOI
https://doi.org/10.1039/B306862E
Article type
Paper
Submitted
19 Jun 2003
Accepted
28 Jul 2003
First published
13 Aug 2003

Org. Biomol. Chem., 2003,1, 3208-3216

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1,5-Asymmetric induction of chirality using π-allyltricarbonyliron lactone complexes: highly diastereoselective synthesis of α-functionalised carbonyl compounds

C. J. Hollowood, S. V. Ley and E. A. Wright, Org. Biomol. Chem., 2003, 1, 3208 DOI: 10.1039/B306862E

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