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Issue 23, 2003
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Efficient syntheses of pterulone, pterulone B and related analogues

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Abstract

An efficient synthesis of the three halogenated naturally occurring products, pterulone (2), pterulone B (3) and alcohol 5, and of a wide range of related unnatural analogues has been achieved starting from the two readily available 1-benzoxepine sulfonyl-containing intermediates 6a and 6b. The biological activities of pterulone and some of the synthesized analogues were tested against a wide spectrum of phytopathogenic fungi.

Graphical abstract: Efficient syntheses of pterulone, pterulone B and related analogues

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Article information


Submitted
09 Jun 2003
Accepted
24 Sep 2003
First published
23 Oct 2003

Org. Biomol. Chem., 2003,1, 4209-4219
Article type
Paper

Efficient syntheses of pterulone, pterulone B and related analogues

P. Lemaire, G. Balme, P. Desbordes and J. Vors, Org. Biomol. Chem., 2003, 1, 4209
DOI: 10.1039/B306356A

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