Issue 2, 2003
From the journal:

Organic & Biomolecular Chemistry

Synthesis and evaluation of N,S-compounds as chiral ligands for transfer hydrogenation of acetophenone†

Jenny K. Ekegren,a   Peter Roth,a   Klas Källström,a   Tibor Tarnai‡a  and  Pher G. Andersson*a  

* Corresponding authors

a Department of Organic Chemistry, Uppsala University, Box 531, SE-751 21 Uppsala, Sweden
E-mail: phera@kemi.uu.se

Abstract

New nitrogen- and sulfur-containing compounds, bicyclic and monocyclic, were prepared and evaluated as ligands in the transfer hydrogenation of acetophenone. Utilising [Ir(COD)Cl]2 as metal precursor the best result, 80% ee, was obtained using a bicyclic sulfoxide ligand.

Graphical abstract: Synthesis and evaluation of N,S-compounds as chiral ligands for transfer hydrogenation of acetophenone

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Article information

DOI
https://doi.org/10.1039/B208907F
Article type
Paper
Submitted
11 Sep 2002
Accepted
05 Nov 2002
First published
09 Dec 2002

Org. Biomol. Chem., 2003,1, 358-366

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Synthesis and evaluation of N,S-compounds as chiral ligands for transfer hydrogenation of acetophenone

J. K. Ekegren, P. Roth, K. Källström, T. Tarnai and P. G. Andersson, Org. Biomol. Chem., 2003, 1, 358 DOI: 10.1039/B208907F

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