Issue 1, 2003
From the journal:

Organic & Biomolecular Chemistry

From central to planar chirality, the first example of atropenantioselective cycloetherification

Gabriela Islas-Gonzalez,a   Michèle Bois-Choussya  and  Jieping Zhu*a  

* Corresponding authors

a Institut de Chimie des Substances Naturelles, CNRS, 91198 Gif-sur-Yvette Cedex, France
E-mail: zhu@icsn.cnrs-gif.fr
Fax: + 33 1 69 07 72 47
Tel: + 33 1 69 82 31 31

Abstract

Using chiral quaternary ammonium hydroxide as base, cycloetherification of linear achiral diarylheptanoid 5, by way of an intramolecular SNAr reaction, provides enantiomerically enriched cyclophane 6 in good to excellent yield.

Graphical abstract: From central to planar chirality, the first example of atropenantioselective cycloetherification

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Article information

DOI
https://doi.org/10.1039/B208905J
Article type
Communication
Submitted
18 Sep 2002
Accepted
07 Oct 2002
First published
08 Nov 2002

Org. Biomol. Chem., 2003,1, 30-32

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From central to planar chirality, the first example of atropenantioselective cycloetherification

G. Islas-Gonzalez, M. Bois-Choussy and J. Zhu, Org. Biomol. Chem., 2003, 1, 30 DOI: 10.1039/B208905J

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