Issue 6, 2003
From the journal:

New Journal of Chemistry

Nonrigid diastereomers: epimerization at chiral metal centers or chiral ligand conformations?

J. W. Faller,a   J. Parra  and  A. R. Lavoiea  

a Department of Chemistry, Yale University, New Haven, CT, USA
E-mail: jack.faller@yale.edu

Abstract

Variable temperature NMR studies of chiral metal complexes can reveal two diastereomers at lower temperatures. A caveat is presented regarding the possibility that chiral ligand conformations may be involved rather than epimeric chiral metal centers.

Graphical abstract: Nonrigid diastereomers: epimerization at chiral metal centers or chiral ligand conformations?

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B302054C
Article type
Opinion
Submitted
12 Feb 2003
Accepted
01 Mar 2003
First published
01 May 2003

New J. Chem., 2003,27, 899-901

Permissions

Request permissions

Nonrigid diastereomers: epimerization at chiral metal centers or chiral ligand conformations?

J. W. Faller, J. Parr and A. R. Lavoie, New J. Chem., 2003, 27, 899 DOI: 10.1039/B302054C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements