A non-interpenetrating 2D coordination polymer from a (CH2)8 spacer-based highly flexible linear ligand and AgCF3CO2

Chun-Long Chen; Cheng-Yong Su; Yue-Peng Cai; Hua-Xin Zhang; An-Wu Xu; Bei-Sheng Kang

doi:10.1039/B301777J

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A non-interpenetrating 2D coordination polymer from a (CH₂)₈ spacer-based highly flexible linear ligand and AgCF₃CO₂†

Chun-Long Chen,^ab Cheng-Yong Su,*^a Yue-Peng Cai,^a Hua-Xin Zhang,^a An-Wu Xu^a and Bei-Sheng Kang*^ab

Author affiliations

* Corresponding authors

^a School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou, China
E-mail: cedc34@zsu.edu.cn

^b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, China

Abstract

Reaction of a (CH₂)₈ spacer-based ligand, 1,8-bis(8-thioquinolyl)octane (C8TQ), with AgCF₃CO₂ affords a designed non-interpenetrating 2D brick-wall coordination polymer [Ag₂(C8TQ)(CF₃CO₂)₂]_n, composed of thio-bridged helical chains racemically aligned and further connected by the (CH₂)₈ spacers, while weak F⋯F interactions between ligated CF₃CO₂⁻ fabricate the 3D supramolecular architecture.

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Supplementary files

Crystal structure data TXT (18K)

Article information

DOI: https://doi.org/10.1039/B301777J
Article type: Letter
Submitted: 13 Feb 2003
Accepted: 13 Mar 2003
First published: 11 Apr 2003

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New J. Chem., 2003,27, 790-792

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A non-interpenetrating 2D coordination polymer from a (CH₂)₈ spacer-based highly flexible linear ligand and AgCF₃CO₂

C. Chen, C. Su, Y. Cai, H. Zhang, A. Xu and B. Kang, New J. Chem., 2003, 27, 790 DOI: 10.1039/B301777J

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