Issue 8, 2003
From the journal:

New Journal of Chemistry

(PPh3-C3H6-PPh3)0.5[NiPS4] and (PPh3-C2H2-PPh3)0.5[NiPS4]: Two new compounds containing [NiPS4]− chains

Servane Coste,a   Martine Bujoli-Doeuff,a   Guy Louarn,b   Dominique Massiot,c   Raymond Breca  and  Stéphane Jobica  

a Institut des Matériaux Jean-Rouxel, Laboratoire de Chimie des Solides, UMR 6502 CNRS - Université de Nantes, 2 rue de la Houssinière, BP 32229, Nantes Cedex 3, France
E-mail: jobic@cnrs-imn.fr
Fax: +33 2 40 37 39 95
Tel: +33 2 40 37 39 17

b Institut des Matériaux Jean-Rouxel, Laboratoire de Physique Cristalline, UMR 6502 CNRS - Université de Nantes, 2 rue de la Houssinière, BP 32229, Nantes Cedex 3, France

c Centre de Recherches sur la physique des Hautes Températures, UPR CNRS 4212, 1D Avenue de la recherche Scientifique, Orléans Cedex 02, France

Abstract

From bowl-like [Ni3P3S12]3− anions containing DMF–KNiPS4 solutions, metathesis experiments were successfully carried out using bi-charged anisotropic organic species and led to two new amorphous (PPh3-C3H6-PPh3)0.5[NiPS4] (I) and (PPh3-C2H2-PPh3)0.5[NiPS4] (II) compounds. Thanks to solid state 31P NMR, Raman and IR spectroscopies, it has been proved that I and II enclose [NiPS4]− chains. Hence, [Ni3P3S12]3− discrete entities can rearrange into chains similar to those observed in the pristine KNiPS4 inorganic materials.

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Article information

DOI
https://doi.org/10.1039/B301148H
Article type
Paper
Submitted
28 Jan 2003
Accepted
07 Apr 2003
First published
30 Jun 2003

New J. Chem., 2003,27, 1228-1232

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(PPh3-C3H6-PPh3)0.5[NiPS4] and (PPh3-C2H2-PPh3)0.5[NiPS4]: Two new compounds containing [NiPS4]− chains

S. Coste, M. Bujoli-Doeuff, G. Louarn, D. Massiot, R. Brec and S. Jobic, New J. Chem., 2003, 27, 1228 DOI: 10.1039/B301148H

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