Issue 3, 2003
From the journal:

New Journal of Chemistry

Copper(ii) is harder than copper(i): a novel mixed-valence example from alkoxide chemistry

Björn Gustafsson,a   Mikael Håkanssonb  and  Susan Jagner*a  

* Corresponding authors

a Department of Inorganic Chemistry, Chalmers University of Technology, Göteborg, Sweden
E-mail: susan@inoc.chalmers.se

b Organic Chemistry, Department of Chemistry, Göteborg University, Göteborg, Sweden

Abstract

Partial oxidation or disproportionation of tetrameric 2-allyl-6-methylphenoxocopper(I) leads to the formation of a novel trinuclear mixed-valence Cu(I)/Cu(II) alkoxide: [Cu3{OC6H3(CH3)[CH2C(H)[double bond, length as m-dash]CH2]}4], in which the central copper(II) atom is coordinated in a distorted square-planar configuration by four oxide ligands, whereas the peripheral copper(I) centres are each bonded to two C[double bond, length as m-dash]C linkages and to two oxide ligands in a tetrahedral arrangement.

Graphical abstract: Copper(ii) is harder than copper(i): a novel mixed-valence example from alkoxide chemistry

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Article information

DOI
https://doi.org/10.1039/B211899H
Article type
Letter
Submitted
29 Nov 2002
Accepted
12 Jan 2003
First published
27 Jan 2003

New J. Chem., 2003,27, 459-461

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Copper(II) is harder than copper(I): a novel mixed-valence example from alkoxide chemistry

B. Gustafsson, M. Håkansson and S. Jagner, New J. Chem., 2003, 27, 459 DOI: 10.1039/B211899H

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