Based on the concept of the transition state of the reactions in a liquid phase as a Prigogine dissipative structure, the following equation has been derived establishing the relationship between the cycloaddition activation energy and thermal effect in a solution: (EaL2L3)/Q = Kx2.
Relationship between the cycloaddition activation energy and thermal effect in solutions
V. G. Uryadov and E. N. Ofitserov, Mendeleev Commun., 2003, 13, 259 DOI: 10.1070/MC2003v013n06ABEH001729
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