The interaction of racemic 1-amino-3-(methylthio)propylphosphinic acid with benzylthiol catalysed by pyridoxal-5'-phosphate-dependent L-methionine-γ-lyase affords (R)-1-amino-3-(benzylthio)propylphosphinic acid, which was converted into the (R)-isomers of phosphinic analogues of homocysteine and methionine.
Chemoenzymatic synthesis of optically active phosphinic analogues of S-substituted sulfur-containing amino acids
K. V. Alferov, Y. N. Zhukov, N. G. Faleev, E. N. Khurs and R. M. Khomutov, Mendeleev Commun., 2003, 13, 127 DOI: 10.1070/MC2003v013n03ABEH001770
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