Issue 3, 2003
From the journal:

Mendeleev Communications

The first chiral derivatives of 1-boraadamantane

Mikhail E. Gurskii,a   Vladimir A. Ponomarev,a   Konstantin A. Lyssenko,b   Mikhail Yu. Antipin,b   Philippe Renaudc  and  Yurii N. Bubnovb  

a N.D.Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation, Leninsky prospekt, 47, Moscow, Russian Federation

b A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russian Federation, ul. Vavilova, 28, Moscow, Russian Federation

c Department of Chemistry and Biochemistry, University of Bern, Bern, Switzerland, Freiestrasse 3, Bern, Switzerland

Abstract

Both (S)-(+)- [(S)-5] and (R)-(–)-2-methyl-1-boraadamantane [(R)-5] were isolated in 96% and 92% ee, respectively, by the crystallization of corresponding (S)-(–)- and (R)-(+)-phenylethylamine adducts from hexane and transformed into optically active 1-hydroxy-2-methyladamantanes by the carbonylation–oxidation sequence.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1070/MC2003v013n03ABEH001791
Article type
Communication
Submitted
30 Apr 2003

Mendeleev Commun., 2003,13, 121-123

Permissions

Request permissions

The first chiral derivatives of 1-boraadamantane

M. E. Gurskii, V. A. Ponomarev, K. A. Lyssenko, M. Yu. Antipin, P. Renaud and Y. N. Bubnov, Mendeleev Commun., 2003, 13, 121 DOI: 10.1070/MC2003v013n03ABEH001791

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements