Racemic (π-pentamethylcyclopentadienyl)(2,2,2-trifluoro-1-phenylethyl diethylphosphinite)rhodium dichloride 2 was found to be a conglomerate, which undergoes spontaneous resolution during crystallization.
Generation of an optically active rhodium(III) complex by crystallization-induced spontaneous resolution of a racemic mixture
I. L. Odinets, O. I. Artyushin, E. V. Sharova, E. I. Goryunov, D. G. Golovanov, K. A. Lyssenko, P. V. Petrovskii and T. A. Mastryukova, Mendeleev Commun., 2003, 13, 102 DOI: 10.1070/MC2003v013n03ABEH001778
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