An examination of transition states in organic liquid-phase reactions including reactant and solvent molecules as Prigogine dissipative structures allowed us to derive a mathematical expression for a so-called linear isokinetic correlation between activation parameters.
Entropy oscillations and isokinetic ratio
V. G. Uryadov and E. N. Ofitserov, Mendeleev Commun., 2003, 13, 39 DOI: 10.1070/MC2003v013n01ABEH001707
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