Jump to main content
Jump to site search

Issue 6, 2003
Previous Article Next Article

Transparent nanohybrids of nanocrystalline TiO2 in PMMA with unique nonlinear optical behavior

Author affiliations

Abstract

PMMA is one of the most versatile polymeric materials for applications in various technological areas including optics and electro-optics. While the current applications of PMMA in optics and electro-optics are limited by their linear optical behavior, we report here in this paper the unique nonlinear optical behavior of nanohybrids consisting of nanocrystalline TiO2 in PMMA. Transparent thin films of TiO2–PMMA nanohybrid on substrates were synthesized by in-situ sol–gel and polymerisation, assisted by spin coating. Using titanium isoproproxide (Ti-iP) as the starting material for nanocrystalline titania, together with methyl methacrylate and 3-(trimethoxysilyl)propyl methacrylate, nanohybrids containing up to 80% Ti-iP in PMMA were successfully realized. The resulting nanohybrid thin films coated on quartz substrates are optically transparent and demonstrate large nonlinear optical behavior, with an ultrafast response of <1.5 ps. The highest two-photon absorption coefficient (β) and nonlinear refractive index (n2) are observed with the nanohybrid thin film of 60 wt% Ti-iP in PMMA, as confirmed by the Z-scan technique.

Graphical abstract: Transparent nanohybrids of nanocrystalline TiO2 in PMMA with unique nonlinear optical behavior

Back to tab navigation

Publication details

The article was received on 04 Dec 2002, accepted on 07 Apr 2003 and first published on 16 Apr 2003


Article type: Paper
DOI: 10.1039/B211976E
Citation: J. Mater. Chem., 2003,13, 1475-1479
  •   Request permissions

    Transparent nanohybrids of nanocrystalline TiO2 in PMMA with unique nonlinear optical behavior

    A. H. Yuwono, J. Xue, J. Wang, H. I. Elim, W. Ji, Y. Li and T. J. White, J. Mater. Chem., 2003, 13, 1475
    DOI: 10.1039/B211976E

Search articles by author

Spotlight

Advertisements