Nanometer-sized copper metal can be formed by UV irradiation of ethanol bis(2,4-pentanedionate)copper(II) solutions: simple tuning of the irradiation conditions switches the process from homogeneous to heterogeneous nucleation, and promotes the formation of either colloidal powders or nanostructured films.
G. G. Condorelli, L. L. Costanzo, I. L. Fragalà, S. Giuffrida and G. Ventimiglia, J. Mater. Chem., 2003, 13, 2409 DOI: 10.1039/B308418C
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