Issue 4, 2003
From the journal:

Journal of Materials Chemistry

Synthesis and stability studies of conformationally locked 4-(diarylamino)aryl- and 4-(dialkylamino)phenyl-substituted second-order nonlinear optical polyenechromophores

Katrin Staub,a   Galina A. Levina,a   Stephen Barlow,*ab   Tony C. Kowalczyk,c   Hilary S. Lackritz,c   Marguerite Barzoukas,d   Alain Fortd  and  Seth R. Marder*abe  

* Corresponding authors

a Beckman Institute, California Institute of Technology, Pasadena, CA 91125, USA

b Department of Chemistry, University of Arizona Tucson, AZ 85721, USA
E-mail: sbarlow@email.arizona.edu

c Gemfire Research, 2440 Embarcadero Way, Palo Alto, CA 94303, USA

d Institut de Physique et Chimie Matériaux de Strasbourg, Groupe d'Optique nonlinéaire et d'Optoélectronique (UM 046 CNRS), rue du Loess 23, Strasbourg Cedex, France

e Optical Sciences Center, University of Arizona Tucson, AZ 85721, USA

Abstract

A series of chromophores with high second-order nonlinearities has been synthesized; the chromphores consist of triarylamine or dialkylarylamine donors linked by a conformationally locked polyene bridge to a dicyanomethylidene acceptor. The use of bridges of this type, combined with the replacement of dialkylarylamine with triarylamine donors, leads to high thermal stability without adverse affects on the nonlinear optical properties of the chromophores.

Graphical abstract: Synthesis and stability studies of conformationally locked 4-(diarylamino)aryl- and 4-(dialkylamino)phenyl-substituted second-order nonlinear optical polyene chromophores

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B208024A
Article type
Paper
Submitted
12 Aug 2002
Accepted
03 Feb 2003
First published
18 Feb 2003

J. Mater. Chem., 2003,13, 825-833

Permissions

Request permissions

Synthesis and stability studies of conformationally locked 4-(diarylamino)aryl- and 4-(dialkylamino)phenyl-substituted second-order nonlinear optical polyene chromophores

K. Staub, G. A. Levina, S. Barlow, T. C. Kowalczyk, H. S. Lackritz, M. Barzoukas, A. Fort and S. R. Marder, J. Mater. Chem., 2003, 13, 825 DOI: 10.1039/B208024A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements