Issue 1, 2003
From the journal:

Green Chemistry

Heptadecafluorooctanesulfonic acid catalyzed ring opening reactions of methylenecyclopropanes with aromatic amines, sulfonamides and alcohols in supercritical carbon dioxide

Min Shi,*a   Yu Chen,b   Bo Xua  and  Jie Tangb  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 354 Fenglin Lu, Shanghai, China

b Department of Chemistry, East China Normal University, 3663 Zhong Shan Bei Lu, Shanghai, China
E-mail: Mshi@pub.sioc.ac.cn
Fax: 86-21-64166128

Abstract

The ring opening reactions of methylenecyclopropanes (MCPs) with ArNH2, RSO2NH2 and alcohols can be carried out in scCO2 in the presence of heptadecafluorooctanesulfonic acid which offer a way to synthesize homoallylic amines, sulfonamides and ethers in environmentally benign conditions.

Graphical abstract: Heptadecafluorooctanesulfonic acid catalyzed ring opening reactions of methylenecyclopropanes with aromatic amines, sulfonamides and alcohols in supercritical carbon dioxide

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Article information

DOI
https://doi.org/10.1039/B210988C
Article type
Paper
Submitted
07 Nov 2002
First published
13 Jan 2003

Green Chem., 2003,5, 85-88

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Heptadecafluorooctanesulfonic acid catalyzed ring opening reactions of methylenecyclopropanes with aromatic amines, sulfonamides and alcohols in supercritical carbon dioxide

M. Shi, Y. Chen, B. Xu and J. Tang, Green Chem., 2003, 5, 85 DOI: 10.1039/B210988C

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