Issue 24, 2003

A coordination network containing non-coordinating polyoxometalate clusters as counterions

Abstract

This report describes the synthesis and characterization of a 2D coordination network that directly incorporates an aniline-functionalized polyoxometalate (POM) cluster. By reacting a cobalt(II) salt of the POM cluster [Mo12O46(AsC6H4NH2)4]4− with a bifunctional ligand, 4,4′-bipyridylethylene, a 2D coordination network was synthesized through a self-assembly process. The POM behaves as a non-coordinating anion and does not interfere with the coordination network other than occupying space. Thermal analysis reveals that the structure is stable to 350 °C.

Graphical abstract: A coordination network containing non-coordinating polyoxometalate clusters as counterions

Supplementary files

Article information

Article type
Paper
Submitted
07 Aug 2003
Accepted
09 Oct 2003
First published
22 Oct 2003

Dalton Trans., 2003, 4678-4681

A coordination network containing non-coordinating polyoxometalate clusters as counterions

B. J. S. Johnson, S. A. Geers, W. W. Brennessel, V. G. Young, Jr. and A. Stein, Dalton Trans., 2003, 4678 DOI: 10.1039/B309453G

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