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Issue 20, 2003
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Syntheses, crystal structures, photophysics and cation-binding studies of luminescent functionalized ruthenium polypyridine complexes with orthometallated aminocarbene ligands

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Abstract

A series of luminescent functionalized ruthenium polypyridine complexes with orthometallated aminocarbene ligands has been synthesized and their photophysical properties studied. The cation-binding properties of one crown-ether functionalized complexes have also been studied. The X-ray crystal structures of [[upper bond 1 start]Ru(bpy)2[double bond, length as m-dash]C(CH2–B15C5)NHC[upper bond 1 end]6H3Br]OTf and [[upper bond 1 start]Ru(5,5′-Me2bpy)2[double bond, length as m-dash]C(CH2Ph)NHC[upper bond 1 end]6H3Br]OTf have been determined (bpy = 2,2′-bipyridine; 5,5′-Me2bpy = 5,5′-dimethyl-2,2′-bipyridine; B15C5 = benzo-15-crown-5).

Graphical abstract: Syntheses, crystal structures, photophysics and cation-binding studies of luminescent functionalized ruthenium polypyridine complexes with orthometallated aminocarbene ligands

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Supplementary files

Article information


Submitted
30 Jun 2003
Accepted
08 Aug 2003
First published
03 Sep 2003

Dalton Trans., 2003, 3914-3921
Article type
Paper

Syntheses, crystal structures, photophysics and cation-binding studies of luminescent functionalized ruthenium polypyridine complexes with orthometallated aminocarbene ligands

V. W. Yam, C. Ko, B. W. Chu and N. Zhu, Dalton Trans., 2003, 3914
DOI: 10.1039/B307429C

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