2-Amino-2-oxazoline and trialkylisourea Pt(ii) complexes derived from organocyanamides
Abstract
In the di(organocyanamide) complexes trans-[PtCl2(NCNR2)2]
(R = Me 1a, Et 1b), prepared by reaction of PtCl2 with the appropriate NCNR2, the cyanamide N
C(OCH2C
H2)NR2}2]
(R = Me 2a, Et 2b) or trialkylisourea trans-[PtCl2{NH
C(OMe)NR2}2]
(R = Me 3a, Et 3b) complexes. The X-ray crystal structure of 2b is also reported, indicating a π-bond delocalization along the N
C
N group of the