Issue 16, 2003
From the journal:

Dalton Transactions

Isolation of a monomeric hybrid zinc phosphate and its one-dimensional relative

Zhi-En Lin,a   You-Wei Yao,b   Jie Zhanga  and  Guo-Yu Yang*a  

* Corresponding authors

a Coordination and Hydrothermal Chemistry Group, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

b Key Laboratory of the Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022, China
E-mail: ygy@ms.fjirsm.ac.cn

Abstract

Two hybrid zinc phosphates, [Zn(phen)]2(H1.5PO4)2(H2PO4) (1) and [Zn(phen)]2(HPO4)(H2PO4)2·xH2O (x ≈ 0.5) (2), have been synthesized under hydrothermal conditions in the presence of 1,10-phenanthroline (phen) ligands. They are the first members in the zinc–phosphate–phen system. The structure of 1 consists of two ZnO3N2 trigonal bipyramids bridged by three P-centered tetrahedra. 1 is novel in the sense that it provides the first example of a monomeric zinc phosphate crystallized in a non-centrosynmmetric space group. The one-dimensional structure of 2 consists of a network of strictly alternating ZnO3N2 trigonal bipyramids, HPO4 and H2PO4 tetrahedra by sharing vertices. Interestingly, the chain-like structure of 2 can be generated from 1 by a shifting of Zn–O–P bonds.

Graphical abstract: Isolation of a monomeric hybrid zinc phosphate and its one-dimensional relative

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Article information

DOI
https://doi.org/10.1039/B304778D
Article type
Paper
Submitted
29 Apr 2003
Accepted
25 Jun 2003
First published
09 Jul 2003

Dalton Trans., 2003, 3160-3164

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Isolation of a monomeric hybrid zinc phosphate and its one-dimensional relative

Z. Lin, Y. Yao, J. Zhang and G. Yang, Dalton Trans., 2003, 3160 DOI: 10.1039/B304778D

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