Issue 16, 2003
From the journal:

Dalton Transactions

X-Ray crystal structures of copper(ii) and cobalt(ii) complexes with Schiff baseligands. Reactivity towards dioxygen

Francis Carré,a   Robert J. P. Corriu,a   Emmanuelle Lancelle-Beltran,a   Ahmad Mehdi,a   Catherine Reyé,*a   Roger Guilard,b   Jan Sýkorac  and  Arie van der Leed  

* Corresponding authors

a Laboratoire de Chimie Moléculaire et Organisation du Solide, UMR 5637 CNRS, Université de Montpellier II, Place E. Bataillon, F-34095 Montpellier Cedex 5, France
E-mail: reye@univ-montp2.fr

b Laboratoire d'Ingénierie Moléculaire pour la Séparation et les Applications des Gaz, LIMSAG, UMR 5633, Université de Bourgogne, 6, Boulevard Gabriel, 21100 Dijon, France
E-mail: limsag@u-bourgogne.fr

c Institute of Chemical Process Fundamentals, Czech Academy of Sciences, Rozvojova 125, 165 02 Prague 6, Czech Republic

d Institut Européen des Membranes, UMR 5635 CNRS, cc 047, Université de Montpellier II, Place E. Bataillon, F-34095 Montpellier, Cedex 5, France

Abstract

Copper(II) and cobalt(II) Schiff base complexes with derivatives of the pentadentate ligand bis(salicylideneimino-3-propyl)amine [H2salDPT] have been prepared. The X-ray crystal structures of the copper(II) complexes Cu[salDPT] and Cu[sal(n-propyltrimethylsilyl)DPT] were determined and revealed five-coordination at the metal centre in both cases. The 1 ∶ 1 dioxygen adduct of Co[sal(n-propyltrimethylsilyl)DPT] was also isolated and its X-ray molecular structure determined.

Graphical abstract: X-Ray crystal structures of copper(ii) and cobalt(ii) complexes with Schiff base ligands. Reactivity towards dioxygen

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Article information

DOI
https://doi.org/10.1039/B304032A
Article type
Paper
Submitted
10 Apr 2003
Accepted
26 Jun 2003
First published
15 Jul 2003

Dalton Trans., 2003, 3211-3215

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X-Ray crystal structures of copper(II) and cobalt(II) complexes with Schiff base ligands. Reactivity towards dioxygen

F. Carré, R. J. P. Corriu, E. Lancelle-Beltran, A. Mehdi, C. Reyé, R. Guilard, J. Sýkora and A. van der Lee, Dalton Trans., 2003, 3211 DOI: 10.1039/B304032A

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