Issue 17, 2003
From the journal:

Dalton Transactions

Synthesis and structure of a new three-dimensional indium phosphate with 16-membered one-dimensional channels†

A Thirumurugana  and  Srinivasan Natarajan*a  

* Corresponding authors

a Framework Solids Laboratory, Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur P.O., Bangalore 560 064, India
E-mail: raj@jncasr.ac.in

Abstract

A new indium phosphate, [NH3(CH2)2NH2(CH2)2NH3]2[NH2(CH2)2NH2(CH2)2NH2][In6.8F8(H2O)2(PO4)4(HPO4)4]·2H2O, I, has been prepared as a good single phase material employing hydrothermal methods using HF–pyridine as the solvent in the presence of diethylenetriamine (DETA). The structure is built-up from vertex linking InO4(H2O)2 and InO4F2 octahedral, and PO4 and PO3(OH) tetrahedral units, giving rise to a three-dimensional structure with large 16-membered one-dimensional channels. The organic amine along with water molecules occupies these channels. The formation of I with In ∶ F > 1 and the presence of large channels are noteworthy features.

Graphical abstract: Synthesis and structure of a new three-dimensional indium phosphate with 16-membered one-dimensional channels

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B303998F
Article type
Paper
Submitted
09 Apr 2003
Accepted
22 Jul 2003
First published
28 Jul 2003

Dalton Trans., 2003, 3387-3391

Permissions

Request permissions

Synthesis and structure of a new three-dimensional indium phosphate with 16-membered one-dimensional channels

A. Thirumurugan and S. Natarajan, Dalton Trans., 2003, 3387 DOI: 10.1039/B303998F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements