Issue 3, 2003
From the journal:

Dalton Transactions

A novel 2D arsenic vanadate network grafted with a transition metal complex: [Cu(phen)]2[VIVV4VAs2O19]·0.5H2O†

Yangguang Li,a   Gejihu De,a   Mei Yuan,a   Enbo Wang,*ab   Rudan Huang,a   Changwen Hu,a   Ninghai Huc  and  Hengqing Jiac  

* Corresponding authors

a Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, P. R. China
E-mail: wangenbo@public.cc.jl.cn

b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, P. R. China

c Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, P. R. China

Abstract

A novel organic–inorganic hybrid compound [Cu(phen)]2[VIVV4VAs2VO19]·0.5H2O 1 has been hydrothermally synthesized. Its structure, determined by single crystal X-ray diffraction, exhibits an unusual two-dimensional arsenic vanadate layered network grafted with the [Cu(phen)]2+ complex. The chelating phen ligands project perpendicularly beyond the inorganic layer. Variable temperature magnetic susceptibility studies indicate that both ferro- and antiferro-magnetic interactions exist in 1.

Graphical abstract: A novel 2D arsenic vanadate network grafted with a transition metal complex: [Cu(phen)]2[VIVV4VAs2O19]·0.5H2O

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Article information

DOI
https://doi.org/10.1039/B210589F
Article type
Paper
Submitted
28 Oct 2002
Accepted
10 Dec 2002
First published
10 Jan 2003

Dalton Trans., 2003, 331-334

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A novel 2D arsenic vanadate network grafted with a transition metal complex: [Cu(phen)]2[VIVV4VAs2O19]·0.5H2O

Y. Li, G. De, M. Yuan, E. Wang, R. Huang, C. Hu, N. Hu and H. Jia, Dalton Trans., 2003, 331 DOI: 10.1039/B210589F

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