Alkali-metal fluoroarsenates(III) revisited; the As4F13− anion, the crystal structure of CsAs4F13 and Raman spectra of MAs4F13(M = Cs, Rb)

Peter Klampfer; Primož Benkič; Bogdan Volavšek; Adolf Jesih

doi:10.1039/B210507A

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Alkali-metal fluoroarsenates(iii) revisited; the As₄F₁₃⁻ anion, the crystal structure of CsAs₄F₁₃ and Raman spectra of MAs₄F₁₃ (M = Cs, Rb)

Peter Klampfer,^a Primož Benkič,^a Bogdan Volavšek^b and Adolf Jesih*^a

Author affiliations

* Corresponding authors

^a Institute Jožef Stefan, Jamova 39, Ljubljana, 1000, Slovenia
E-mail: adolf.jesih@ijs.si

^b Faculty of Chemistry and Chemical Engineering, Smetanova 17, 2000 Maribor, Slovenia
E-mail: bogdan.volavsek@uni-mb.si

Abstract

Alkali-metal tridecafluorotetraarsenates(III), CsAs₄F₁₃ and RbAs₄F₁₃ were synthesized by the reaction of CsF and RbF with liquid AsF₃ at 353 K.

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Supplementary files

Crystal structure data TXT (15K)

Article information

DOI: https://doi.org/10.1039/B210507A
Article type: Communication
Submitted: 25 Oct 2002
Accepted: 06 Dec 2002
First published: 16 Dec 2002

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Dalton Trans., 2003, 163-164

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Alkali-metal fluoroarsenates(III) revisited; the As₄F₁₃⁻ anion, the crystal structure of CsAs₄F₁₃ and Raman spectra of MAs₄F₁₃ (M = Cs, Rb)

P. Klampfer, P. Benkič, B. Volavšek and A. Jesih, Dalton Trans., 2003, 163 DOI: 10.1039/B210507A

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Dalton Transactions