Issue 4, 2003
From the journal:

Dalton Transactions

New self-assembled one-dimensional nickel coordination polymers and hydrogen-bonded networks

Dejana Vujovic,a   Helgard G. Raubenheimera  and  Luigi R. Nassimbenib  

a Department of Chemistry, University of Stellenbosch, Private Bag X1, Matieland 7602, South Africa

b Department of Chemistry, University of Cape Town, Rondebosch 7701, South Africa

Abstract

Reaction of Ni(NCS)2 with aminobenzonitrile (ABN) isomers in solution gave rise to the formation of five coordination polymers of the general formula [Ni(NCS)2(ABN)2]n consisting of one-dimensional chains with adjacent nickel centres linked by bridging NCS− or ABN ligands. The compounds were characterised by single crystal X-ray diffraction, X-ray powder diffraction, infrared spectroscopy, thermogravimetry, differential scanning calorimetry and mass spectrometry.

Graphical abstract: New self-assembled one-dimensional nickel coordination polymers and hydrogen-bonded networks

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Article information

DOI
https://doi.org/10.1039/B206638F
Article type
Paper
Submitted
09 Jul 2002
Accepted
04 Dec 2002
First published
23 Jan 2003

Dalton Trans., 2003, 631-637

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New self-assembled one-dimensional nickel coordination polymers and hydrogen-bonded networks

D. Vujovic, H. G. Raubenheimer and L. R. Nassimbeni, Dalton Trans., 2003, 631 DOI: 10.1039/B206638F

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