Application of integral encounter theory to account for spin effects in radical reactions: Photochemical generation and spin selective recombination of radical ions
Abstract
Within the framework of the integral encounter theory a consistent description is given for the processes of photochemical generation and spin selective recombination of radical ions. The kinetic equations obtained can be used for the analysis of the data of various experimental spin chemistry techniques. A detailed theoretical analysis of the photoconductivity detected magnetic resonance (PCDMR) kinetics is performed.