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Issue 18, 2003
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Synthesis of neutral nickel catalysts for ethylenepolymerization – the influence of ligand size on catalyst stability

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Abstract

A facile synthesis of nickel salicylaldimine complexes with labile dissociating ligands is described. In addition to producing highly active ethylene polymerization catalysts, important insights into the effect of ligand size on catalyst stability and information on the mechanism of polymerization are provided.

Graphical abstract: Synthesis of neutral nickel catalysts for ethylene polymerization – the influence of ligand size on catalyst stability

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Supplementary files

Article information


Submitted
12 Jun 2003
Accepted
30 Jul 2003
First published
15 Aug 2003

Chem. Commun., 2003, 2272-2273
Article type
Communication

Synthesis of neutral nickel catalysts for ethylene polymerization – the influence of ligand size on catalyst stability

E. F. Connor, T. R. Younkin, J. I. Henderson, A. W. Waltman and R. H. Grubbs, Chem. Commun., 2003, 2272
DOI: 10.1039/B306701G

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