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Issue 11, 2003
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Trimethyltriazacyclohexane as bridging ligand for triangular Cu3 units and C–H hydride abstraction into a Cu6 cluster

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Abstract

Reaction of [Cu(MeCN)4](BF4) with N,N′,N″-trimethyl-1,3,5-triazacyclohexane in CH2Cl2 leads to two Cu6 clusters containing the triazacyclohexane as a ligand to triangular Cu3 units with the abstraction and incorporation of chloride and hydride.

Graphical abstract: Trimethyltriazacyclohexane as bridging ligand for triangular Cu3 units and C–H hydride abstraction into a Cu6 cluster

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Publication details

The article was received on 11 Mar 2003, accepted on 03 Apr 2003 and first published on 02 May 2003


Article type: Communication
DOI: 10.1039/B302670A
Citation: Chem. Commun., 2003,0, 1272-1273
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    Trimethyltriazacyclohexane as bridging ligand for triangular Cu3 units and C–H hydride abstraction into a Cu6 cluster

    R. D. Köhn, Z. Pan, M. F. Mahon and G. Kociok-Köhn, Chem. Commun., 2003, 0, 1272
    DOI: 10.1039/B302670A

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