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Issue 7, 2003
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Dilithiated phosphazenes: scaffolds for the synthesis of olefins through a new class of bicyclic 1,2-oxaphosphetanes

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Abstract

The first examples of the PN-directed dilithiation of (N-methoxycarbonyl)phosphazenes in the Cα and Cortho to the phosphorus, and the use of these dianions in the formation of tri- and tetra-substituted olefins through stereospecific thermolysis of a new type of isolable bicyclic 1,2-oxaphosphetanes are described.

Graphical abstract: Dilithiated phosphazenes: scaffolds for the synthesis of olefins through a new class of bicyclic 1,2-oxaphosphetanes

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Publication details

The article was received on 23 Dec 2002, accepted on 14 Feb 2003 and first published on 03 Mar 2003


Article type: Communication
DOI: 10.1039/B212708C
Citation: Chem. Commun., 2003,0, 856-857
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    Dilithiated phosphazenes: scaffolds for the synthesis of olefins through a new class of bicyclic 1,2-oxaphosphetanes

    J. García-López, E. Peralta-Pérez, A. Forcén-Acebal, S. García-Granda and F. López-Ortiz, Chem. Commun., 2003, 0, 856
    DOI: 10.1039/B212708C

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