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Issue 6, 2003
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The first example of enantioselective isocyanosilylation of mesoepoxides with TMSCN catalyzed by novel chiral organogallium and indium complexes

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Abstract

The desymmetrization ring opening of meso epoxides using trimethylsilyl cyanide catalyzed by organogallium and indium complexes with binaphthol monoether derivatives as chiral ligands gave β-isocyanohydrins with moderate to excellent enantioselectivities of up to 95% ee.

Graphical abstract: The first example of enantioselective isocyanosilylation of meso epoxides with TMSCN catalyzed by novel chiral organogallium and indium complexes

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Article information


Submitted
17 Dec 2002
Accepted
24 Jan 2003
First published
13 Feb 2003

Chem. Commun., 2003, 692-693
Article type
Communication

The first example of enantioselective isocyanosilylation of meso epoxides with TMSCN catalyzed by novel chiral organogallium and indium complexes

C. Zhu, F. Yuan, W. Gu and Y. Pan, Chem. Commun., 2003, 692
DOI: 10.1039/B212511K

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