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Issue 3, 2003
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A novel three-dimensional coordination polymer constructed with mixed-valence dimeric copper(I,II) units

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Abstract

A novel three-dimensional coordination polymer with a mixed-valence localized copper(I,II) dimeric unit, [Cu2(4-pya)3]n (4-pya = 4-pyridinecarboxylate), was hydrothermally synthesized via a simultaneous in-situa redox and hydrolysis reaction of Cu(II) and 4-cyanopyridine and crystallographically characterized to be a twofold interpenetrated three-dimensional coordination network with a cubic [Cu16(4-pya)12] building unit.

Graphical abstract: A novel three-dimensional coordination polymer constructed with mixed-valence dimeric copper(i,ii) units

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Publication details

The article was received on 06 Nov 2002, accepted on 17 Dec 2002 and first published on 15 Jan 2003


Article type: Communication
DOI: 10.1039/B210914J
Citation: Chem. Commun., 2003,0, 428-429
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    A novel three-dimensional coordination polymer constructed with mixed-valence dimeric copper(I,II) units

    M. Tong, L. Li, K. Mochizuki, H. Chang, X. Chen, Y. Li and S. Kitagawa, Chem. Commun., 2003, 0, 428
    DOI: 10.1039/B210914J

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