Issue 23, 2003
From the journal:

Chemical Communications

Efficient preparation of 1,4,8-trimethylcyclam and its conversion into a thioalkyl-pendant pentadentate chelate

Jason A. Halfen*a  and  Victor G. Young, Jr.b  

* Corresponding authors

a Department of Chemistry, University of Wisconsin-Eau Claire, Eau Claire, WI 54702, USA
E-mail: halfenja@uwec.edu
Fax: 715-836-4979
Tel: 715-836-4360

b Department of Chemistry, University of Minnesota, 207 Pleasant St. S.E., Minneapolis, MN 55455, USA
E-mail: young@chem.umn.edu
Fax: 612-626-7541
Tel: 612-625-6897

Abstract

A facile synthesis of 1,4,8-trimethylcyclam and a thioalkyl-pendant derivative are reported, and the X-ray crystal structure of a nickel(II) complex illustrates structural consequences of appending the thiolate donor onto the macrocycle.

Graphical abstract: Efficient preparation of 1,4,8-trimethylcyclam and its conversion into a thioalkyl-pendant pentadentate chelate

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Article information

DOI
https://doi.org/10.1039/B311520H
Article type
Communication
Submitted
19 Sep 2003
Accepted
03 Oct 2003
First published
22 Oct 2003

Chem. Commun., 2003, 2894-2895

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Efficient preparation of 1,4,8-trimethylcyclam and its conversion into a thioalkyl-pendant pentadentate chelate

J. A. Halfen and V. G. Young, Jr., Chem. Commun., 2003, 2894 DOI: 10.1039/B311520H

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