Issue 24, 2003
From the journal:

Chemical Communications

Use and recovery of a homogeneous catalyst with carbon dioxide as a solubility switch†

Christopher D. Ablan,a   Jason P. Hallett,b   Kevin N. West,b   Rebecca S. Jones,b   Charles A. Eckert,b   Charles L. Liottab  and  Philip G. Jessop‡*a  

* Corresponding authors

a Department of Chemistry, University of California, Davis, California 95616-5295, USA
E-mail: jessop@chem.ucdavis.edu
Fax: +1 (530) 752-8995
Tel: +1 (530) 759-9773

b Schools of Chemistry and Chemical Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0100, USA
E-mail: cae@che.gatech.edu
Fax: +1 (404) 894-9085
Tel: +1 (404) 894-7070

Abstract

A method for fluorous biphasic catalysis is described, in which the fluorous liquid is replaced by fluorinated silica, the fluorous catalyst is induced to dissolve in the organic solvent by the presence of CO2, and the recovery of the catalyst after the reaction is achieved by release of the CO2 pressure.

Graphical abstract: Use and recovery of a homogeneous catalyst with carbon dioxide as a solubility switch

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B311146F
Article type
Communication
Submitted
12 Sep 2003
Accepted
09 Oct 2003
First published
03 Nov 2003

Chem. Commun., 2003, 2972-2973

Permissions

Request permissions

Use and recovery of a homogeneous catalyst with carbon dioxide as a solubility switch

C. D. Ablan, J. P. Hallett, K. N. West, R. S. Jones, C. A. Eckert, C. L. Liotta and P. G. Jessop, Chem. Commun., 2003, 2972 DOI: 10.1039/B311146F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements