Issue 21, 2003
From the journal:

Chemical Communications

A versatile synthesis of new pyrimidinyl nitronyl nitroxides†

P. Brough,a   R. Chiarelli,b   J. Pécaut,a   A. Rassat*b  and  P. Rey*a  

* Corresponding authors

a Département de Recherche Fondamentale sur la Matiére Condensée, Service de Chimie Inorganique et Biologique, (UMR CNRS 5046), 17 Rue des Martyrs F38054, Grenoble Cedex 09, France
E-mail: rey@drfmc.ceng.cea.fr
Fax: 0033 438 785090
Tel: 0033 438 783568

b Ecole Normale Supérieure, Département de Chimie, (UMR 8640,CNRS-ENS-Université Paris VI ), 24 Rue Lhomond, F75231, Paris Cedex 05, France
E-mail: andre.rassat@ens.fr
Fax: 0033 144 323325
Tel: 0033 144 323266

Abstract

Pyrimidinyl nitronyl nitroxides where the bis-N-oxy fragment is included in a six-membered ring were prepared from diacetonamine by a sequence of reactions including a Grignard reaction, a Ritter reaction and oxidation of the intermediate pyrimidine; the properties of the 2-phenyl-substituted representative are fully described.

Graphical abstract: A versatile synthesis of new pyrimidinyl nitronyl nitroxides

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Article information

DOI
https://doi.org/10.1039/B309786B
Article type
Communication
Submitted
14 Aug 2003
Accepted
17 Sep 2003
First published
02 Oct 2003

Chem. Commun., 2003, 2722-2723

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A versatile synthesis of new pyrimidinyl nitronyl nitroxides

P. Brough, R. Chiarelli, J. Pécaut, A. Rassat and P. Rey, Chem. Commun., 2003, 2722 DOI: 10.1039/B309786B

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