Issue 22, 2003
From the journal:

Chemical Communications

Formation of nickel-thiolate aggregates via reaction with CH2Cl2

Qiang Wang,a   Andrew C. Marr,a   Alexander J. Blake,a   Claire Wilsona  and  Martin Schröder*a  

* Corresponding authors

a School of Chemistry, The University of Nottingham, Nottingham, UK
E-mail: M.Schroder@nottingham.ac.uk
Fax: + 44(0)115 9513563
Tel: + 44(0)115 9513490

Abstract

Reaction of the mononuclear nickel-thiolate complex [Ni(L1)(dppe)] with CH2Cl2 affords the novel pentanuclear complex [Ni5Cl2(L1)4(dppe)2], while [Ni(L1)(dcpe)] reacts with CH2Cl2 to give the binuclear species [Ni2Cl2(L2)(dcpe)2] in which two L1 units are linked by a methylene group derived from CH2Cl2.

Graphical abstract: Formation of nickel-thiolate aggregates via reaction with CH2Cl2

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B309523A
Article type
Communication
Submitted
08 Aug 2003
Accepted
18 Sep 2003
First published
20 Oct 2003

Chem. Commun., 2003, 2776-2777

Permissions

Request permissions

Formation of nickel-thiolate aggregates via reaction with CH2Cl2

Q. Wang, A. C. Marr, A. J. Blake, C. Wilson and M. Schröder, Chem. Commun., 2003, 2776 DOI: 10.1039/B309523A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements