Issue 23, 2003
From the journal:

Chemical Communications

Controlled haptotropic rearrangements – towards a stereospecific molecular switch based on chiral arene chromium complexes†‡

Holger C. Jahr,a   Martin Niegerb  and  Karl Heinz Dötz*a  

* Corresponding authors

a Kekulé-Institut für Organische Chemie und Biochemie, Rheinische Friedrich-Wilhelms-Universität, Gerhard-Domagk-Straße 1, 53121 Bonn, Germany
E-mail: doetz@uni-bonn.de
Fax: 49 228 73 5813
Tel: 49 228 73 5609

b Institut für Anorganische Chemie, Rheinische Friedrich-Wilhelms-Universität, Gerhard-Domagk-Straße 1, 53121 Bonn, Germany

Abstract

A stereospecific molecular switch has been designed based on a reversible thermo- or photo-induced haptotropic shift of a Cr(CO)3 fragment along a naphthohydroquinone skeleton.

Graphical abstract: Controlled haptotropic rearrangements – towards a stereospecific molecular switch based on chiral arene chromium complexes

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Article information

DOI
https://doi.org/10.1039/B307487K
Article type
Communication
Submitted
01 Jul 2003
Accepted
24 Sep 2003
First published
23 Oct 2003

Chem. Commun., 2003, 2866-2867

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Controlled haptotropic rearrangements – towards a stereospecific molecular switch based on chiral arene chromium complexes

H. C. Jahr, M. Nieger and K. Heinz Dötz, Chem. Commun., 2003, 2866 DOI: 10.1039/B307487K

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