Issue 19, 2003
From the journal:

Chemical Communications

Neutral nido-heteroboranes with non ionisable hydrogen as arenes in coordination†

Oscar Tutusaus,‡a   Clara Viñas,a   Raikko Kivekäs,b   Reijo Sillanpääc  and  Francesc Teixidor*a  

* Corresponding authors

a Institut de Ciència de Materials de Barcelona, Campus de la U.A.B., E-08193 Bellaterra, Spain
E-mail: teixidor@icmab.es
Fax: (+34) 93 5805729
Tel: (+34)93 5801853

b Department of Chemistry, University of Helsinki, P.O. Box 55, FIN-00014 Helsinki, Finland

c Department of Chemistry, University of Jyväskylä, FIN-40351 Jyväskylä, Finland

Abstract

Designed ligands have been synthesised to produce the first arene-like metallacarborane. For arene-like coordination the number of electronegative elements on the coordinating site must be kept to a minimum. Choosing ligands with bulky substituents on the heteroatom allows easy rearrangement and arene-like coordination. This is more hampered the higher the number of hetereoatoms to be re-located.

Graphical abstract: Neutral nido-heteroboranes with non ionisable hydrogen as arenes in coordination

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Article information

DOI
https://doi.org/10.1039/B307027A
Article type
Communication
Submitted
19 Jun 2003
Accepted
06 Aug 2003
First published
21 Aug 2003

Chem. Commun., 2003, 2458-2459

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Neutral nido-heteroboranes with non ionisable hydrogen as arenes in coordination

O. Tutusaus, C. Viñas, R. Kivekäs, R. Sillanpää and F. Teixidor, Chem. Commun., 2003, 2458 DOI: 10.1039/B307027A

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