Unprecedented detection of inherent chirality in uranyl–salophen complexes

Abstract

In complexes with the uranyl dication salophen ligands are highly puckered. This implies that non-symmetrically substituted uranyl–salophen derivatives exist in principle as a pair of enantiomers. However, due to easy disrotations about the bonds connecting the phenoxide units to the imine carbons, the rate of interconversion between enantiomeric forms of simple, sterically unhindered compounds is extremely fast. Bulky substituents in appropriate positions decrease the interconversion rate and make this novel type of inherent chirality detectable by ¹H and ¹³C NMR.