Issue 17, 2003
From the journal:

Chemical Communications

Highly stereoselective, thermodynamically controlled and reversible formation of a new P-chiral phosphine

Igor V. Komarov,*a   Anke Spannenberg,a   Jens Holza  and  Armin Börner*ab  

* Corresponding authors

a Leibniz-Institut für Organische Katalyse an der Universität Rostock e.V., Buchbinderstraße 5/6, D-18055 Rostock, Germany
E-mail: ik214@yahoo.com

b Fachbereich Chemie der Universität Rostock, Albert-Einstein-Str. 3a, D-18059 Rostock, Germany
E-mail: armin.boerner@chemie.uni-rostock.de

Abstract

The highly stereoselective formation of a chiral α-hydroxyphospholane under very mild condition is reported, taking place on a camphor skeleton by an intramolecular thermodynamically controlled and reversible addition of an epimeric secondary phosphine group to a carbonyl group.

Graphical abstract: Highly stereoselective, thermodynamically controlled and reversible formation of a new P-chiral phosphine

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Article information

DOI
https://doi.org/10.1039/B306153A
Article type
Communication
Submitted
30 May 2003
Accepted
15 Jul 2003
First published
31 Jul 2003

Chem. Commun., 2003, 2240-2241

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Highly stereoselective, thermodynamically controlled and reversible formation of a new P-chiral phosphine

I. V. Komarov, A. Spannenberg, J. Holz and A. Börner, Chem. Commun., 2003, 2240 DOI: 10.1039/B306153A

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