Issue 17, 2003

Ring-opening polymerization of gold macrocycles and self-assembly of a coordination polymer through hydrogen-bonding

Abstract

The equilibrium between digold and tetragold rings and a ring-opened oligomer and polymer is established by NMR and ESI-MS studies in solution and by structure determinations in the solid state; the polymer containing amide-derivatized ligands undergoes self-assembly through hydrogen bonding to give an ordered network.

Graphical abstract: Ring-opening polymerization of gold macrocycles and self-assembly of a coordination polymer through hydrogen-bonding

Supplementary files

Article information

Article type
Communication
Submitted
28 May 2003
Accepted
21 Jul 2003
First published
31 Jul 2003

Chem. Commun., 2003, 2228-2229

Ring-opening polymerization of gold macrocycles and self-assembly of a coordination polymer through hydrogen-bonding

T. J. Burchell, D. J. Eisler, M. C. Jennings and R. J. Puddephatt, Chem. Commun., 2003, 2228 DOI: 10.1039/B306004G

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