Issue 17, 2003
From the journal:

Chemical Communications

Luminescent heterohexanuclear complexes with platinum alkynyl and silver diphosphine as components

Qiao-Hua Wei,a   Gang-Qiang Yin,a   Zhen Ma,a   Lin-Xi Shia  and  Zhong-Ning Chen*ab  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
E-mail: czn@ms.fjirsm.ac.cn
Fax: +86 591 379 2346

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Abstract

Reactions between the building blocks [Ag2(μ-Ph2PXPPh2)2(MeCN)2]2+ and [Pt(C[triple bond, length as m-dash]CC6H4R-p)4]2− (R = H, CH3) afforded strongly luminescent acetylide-linked neutral heterohexanuclear complexes Pt2Ag4(μ-Ph2PNPPh2)4 (C[triple bond, length as m-dash]CC6H4R-p)4 (R = H, 1; CH3, 2) for X = NH, but a heterotrinuclear complex cation [PtAg2(μ-PPh2CH2PPh2)2 (C[triple bond, length as m-dash]CC6H5)2(CH3CN)2]2+ (32+) for X = CH2.

Graphical abstract: Luminescent heterohexanuclear complexes with platinum alkynyl and silver diphosphine as components

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Article information

DOI
https://doi.org/10.1039/B305284B
Article type
Communication
Submitted
14 May 2003
Accepted
10 Jul 2003
First published
21 Jul 2003

Chem. Commun., 2003, 2188-2189

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Luminescent heterohexanuclear complexes with platinum alkynyl and silver diphosphine as components

Q. Wei, G. Yin, Z. Ma, L. Shi and Z. Chen, Chem. Commun., 2003, 2188 DOI: 10.1039/B305284B

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