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Issue 18, 2003
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Tris(triphenylplumbyl)plumbate: an anion with three stretched lead–lead bonds

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Abstract

Treatment of lead(II) bromide with phenylmagnesium bromide at low temperature furnishes yellow crystals of the ionic compound [BrMg(THF)5]+ [:Pb(PbPh3)3] which, upon X-ray crystallographic analysis, reveals three stretched Pb–Pb bonds and Pb–Pb–Pb angles of about 93°.

Graphical abstract: Tris(triphenylplumbyl)plumbate: an anion with three stretched lead–lead bonds

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Publication details

The article was received on 09 May 2003, accepted on 25 Jul 2003 and first published on 11 Aug 2003


Article type: Communication
DOI: 10.1039/B305217F
Citation: Chem. Commun., 2003,0, 2342-2343

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    Tris(triphenylplumbyl)plumbate: an anion with three stretched lead–lead bonds

    F. Stabenow, W. Saak and M. Weidenbruch, Chem. Commun., 2003, 0, 2342
    DOI: 10.1039/B305217F

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