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Issue 16, 2003
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A facile and novel route to unprecedented manganese C4 cumulenic complexes

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Abstract

The theoretically characterized (DFT) C4 cumulenic species Mn(C5H4R)(dmpe) {[double bond, length as m-dash]C[double bond, length as m-dash]C[double bond, length as m-dash]C[double bond, length as m-dash]C(SnPh3)2} was obtained by photolysis of the Csp2–Sn bond in the vinylidene complex Mn(C5H4R)(dmpe)[[double bond, length as m-dash]C[double bond, length as m-dash]C(SnPh3)–C[triple bond, length as m-dash]CSnPh3], which in turn was prepared by a thermal reaction from MnC5H4R(dmpe)(C7H8) and Ph3Sn–C4–SnPh3.

Graphical abstract: A facile and novel route to unprecedented manganese C4 cumulenic complexes

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Publication details

The article was received on 30 Apr 2003, accepted on 16 Jun 2003 and first published on 09 Jul 2003


Article type: Communication
DOI: 10.1039/B304882A
Citation: Chem. Commun., 2003,0, 2006-2008
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    A facile and novel route to unprecedented manganese C4 cumulenic complexes

    K. Venkatesan, F. J. Fernández, O. Blacque, T. Fox, M. Alfonso, H. W. Schmalle and H. Berke, Chem. Commun., 2003, 0, 2006
    DOI: 10.1039/B304882A

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