Issue 15, 2003
From the journal:

Chemical Communications

Synthesis and catalytic activity of a chiral periodic mesoporous organosilica (ChiMO)

Carlos Baleizão,ab   Bárbara Gigante,*a   Debasish Das,b   Mercedes Alvaro,b   Hermenegildo Garcia*b  and  Avelino Corma*b  

* Corresponding authors

a INETI- Departamento de Tecnologia das Industrias Químicas, Estrada do Paço do Lumiar, 22, 1649-038 Lisboa, Portugal

b Instituto de Tecnología Química/CSIC-Av. de los Naranjos, s/n, 46022 Valencia, Spain
E-mail: acorma@itq.upv.es
Fax: +343877809
Tel: +34963877800

Abstract

A chiral vanadyl salen complex having two peripheral trimethoxysilyl groups has been used to obtain a chiral periodic mesoporous organosilica having MCM-41 periodicity and the two Si–CH2 groups anchored on the framework; this solid induces 30 % enantioselectivity in the cyanosilylation of benzaldehyde.

Graphical abstract: Synthesis and catalytic activity of a chiral periodic mesoporous organosilica (ChiMO)

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Article information

DOI
https://doi.org/10.1039/B304814D
Article type
Communication
Submitted
30 Apr 2003
Accepted
27 May 2003
First published
18 Jun 2003

Chem. Commun., 2003, 1860-1861

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Synthesis and catalytic activity of a chiral periodic mesoporous organosilica (ChiMO)

C. Baleizão, B. Gigante, D. Das, M. Alvaro, H. Garcia and A. Corma, Chem. Commun., 2003, 1860 DOI: 10.1039/B304814D

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