Issue 14, 2003
From the journal:

Chemical Communications

Synthesis, structure and catalytic activity of an air-stable titanium triflate, supported by an amine tris(phenolate) ligand†

Steven D. Bull,a   Matthew G. Davidson,a   Andrew L. Johnson,a   Diane E. J. E. Robinsona  and  Mary F. Mahonb  

a Department of Chemistry, University of Bath, Claverton Down, Bath, UK
E-mail: s.d.bull@bath.ac.uk, m.g.davidson@bath.ac.uk
Fax: +44 (0)1225 386231
Tel: +44 (0)1225 386443

b Bath Chemical Crystallography Unit, Department of Chemistry, University of Bath, Claverton Down, Bath, UK
Fax: +44 (0)1225 386231
Tel: +44 (0)1225 383752

Abstract

An air- and moisture-stable titanium(IV) triflate, 3, supported by a C3-symmetric amine tris(phenolate) ligand has been synthesised, characterised by X-ray crystallography and demonstrated to be an excellent catalyst for formal aza-Diels–Alder reactions.

Graphical abstract: Synthesis, structure and catalytic activity of an air-stable titanium triflate, supported by an amine tris(phenolate) ligand

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DOI
https://doi.org/10.1039/B304704K
Article type
Communication
Submitted
30 Apr 2003
Accepted
30 May 2003
First published
18 Jun 2003

Chem. Commun., 2003, 1750-1751

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Synthesis, structure and catalytic activity of an air-stable titanium triflate, supported by an amine tris(phenolate) ligand

S. D. Bull, M. G. Davidson, A. L. Johnson, D. E. J. E. Robinson and M. F. Mahon, Chem. Commun., 2003, 1750 DOI: 10.1039/B304704K

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